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As a new enemy emerges seven months after Slade’s attack upon Starling City, Oliver battles with the help of his teammate Roy. However, with the Arrow’s presence elsewhere someone he had loved dearly is hurt.
Lance calls the Arrow when another archer appears in town and starts skewering businessmen. Diggle uses A.R.G.U.S. to find the archer’s identity; he is a man named Simon Lacroix, who goes by the codename Komodo. However, the team hits a rough patch with the mission and gets help from a surprising source – Laurel. Meanwhile, Oliver begins to worry that he hasn’t heard from Thea, which forces Roy to tell him the truth about why she left town. Ray Palmer pursues Felicity. In the flashback, Maseo tells Oliver that Amanda Waller has ordered his first kill. As Oliver looks down the scope of the rifle, he sees the target is his best friend, Tommy. Despite her promise to her sister, Laurel debates sharing a secret about Sara with Lance.
Oliver decides it’s time for Thea to come back to Starling City, so he packs for Corto Maltese, where Felicity has traced Thea’s whereabouts. Lyla asks Diggle to go with Oliver because one of her field operatives, Mark Shaw, has gone dark in Corto Maltese and she’d like him to look into it. Feeling responsible for Thea’s departure, Roy joins Oliver and Diggle on their journey. Shaw double-crosses Diggle, putting numerous A.R.G.U.S. agents, including Lyla, at risk. Meanwhile, Laurel meets Ted Grant, and Felicity adjusts to her new job.
A furious Nyssa confronts Oliver about Sara. When Oliver learns Malcolm Merlyn is alive, he suspects Merlyn killed Sara. Oliver and Nyssa join forces and go after the Dark Archer, intent on bringing Sara’s killer to justice. Laurel keeps her distance from Nyssa, as she blames her sister’s death on her involvement with the League of Assassins. Meanwhile, Oliver and Roy work on repairing their respective relationships.
When a cyber attack brings Starling City to its knees, Oliver and Felicity are pushed to their limits to contain the destruction. Life gets even more complicated for Felicity when her mother, Donna, stops by for a surprise visit. Meanwhile, Ted Grant questions Laurel’s motives, and Thea buys an apartment with Malcolm’s “estate” money, which infuriates Oliver.
After a body is found strung up in the Wildcat gym, Ted Grant becomes the main suspect. Oliver and Laurel argue over Ted’s innocence. Meanwhile, in flashbacks, when Maseo needs Oliver to remember where an informant for China White stashed key information, he asks Tatsu to help jog Oliver’s memory. Roy shares a secret with Felicity.
Oliver must stop an Arrow-obsessed serial killer, Carrie Cutter, who is convinced that The Arrow is her one true love and will stop at nothing to get his attention. Unfortunately, her way of getting his attention is to kill people. Meanwhile, Ray asks Felicity to be his date for a work dinner with important clients. Thea auditions new DJs for Verdant and meets Chase, a brash DJ with whom she immediately clashes.
As Oliver, Arsenal, and Diggle pursue a killer named Digger Harkness, they encounter an ARGUS team; Oliver and the Flash team up to try and stop Harkness.
The League of Assassins give Oliver 48 hours to find Sara’s killer, or Starling City citizens will die. Oliver then has an epic confrontation with Ra’s al Ghul.
The Team’s worst fears are realized when Merlyn informs them of Oliver’s death. Meanwhile Ray Palmer tests part of his ATOM suit out and Laurel Lance decides to pursue justice outside of the law by taking up the mantle of the Black Canary.
Arsenal and Diggle confront Laurel about trying to step into her sister’s shoes and warn her to stop before she gets herself killed. However, the villan Brick kidnaps the city’s Aldermen and threatens to kill them all unless the police evacuate The Glades, it’s all suits on deck. Meanwhile, Ray steps in to help Lance and the police force fight Brick, showing Felicity a new side of her boss. Malcolm tells them that Ra’s al Ghul is after his family and they must leave town immediately.
Still operating without Oliver and desperate to stop Brick, Team Arrow is forced to consider Malcolm’s offer to help shut Brick down as Malcolm has a personal score to settle with the felon. Roy and Laurel point out that the team could use some help to save the innocents of The Glades, but Felicity is adamantly against it. They look to Diggle to make the final decision. Meanwhile, the flashbacks chronicle Malcolm’s descent from kind-hearted father and husband to cold-blooded killer after the murder of his wife.
Oliver struggles to adjust to the changes that have taken place within Team Arrow; Laurel ignores Oliver and pursues Vertigo – who injects her with the drug; Thea receives a surprise visitor.
Malcolm puts Oliver and Thea in a dangerous situation that lands them on Lian Yu with Oliver’s former enemy, Deathstroke. A flashback reveals when Oliver and Maseo returned to Starling City to retrieve the Omega bioweapon, and despite being under strict orders from Amanda Waller not to reveal himself to anyone, Oliver looks in on his family, Laurel and Tommy.
Malcolm is captured by Ra’s al Ghul and taken to Nanda Parbat. Because of his love for Thea, Oliver considers saving Merlyn. Ray is obsessed with finishing his Atom suit so he can save the city but Felicity fears he is heading down the same path as Oliver and tries to pull him out of the lab.
Oliver thinks about the offer Ra’s Al Ghul gave him, but to do so there’s a catch.
It’s celebration time as Diggle and Lyla get married. However, Deadshot interrupts their honeymoon and tells them the Suicide Squad has been given a new mission – rescue United States Senator Joseph Cray from a hostage situation in the Republic of Kasnia. Amanda Waller breaks down the mission and introduced them to the newest member of the Suicide Squad, Cupid. Meanwhile, Oliver learns about Ray’s new Atom costume and the two have a heated stand-off. Felicity and Ray hit a rough patch.
During an attack on the mayor’s office, Ray is critically injured. Felicity is pleasantly surprised when her mother, Donna Smoak, shows up at the hospital to offer her support. With the SCPD out in full force looking for the assailant, Oliver and his team work hard to stay one step ahead of the police to find the man responsible. However, things come to a head when Ra’s al Ghul kidnaps Captain Lance.
Jake Simmons, a metahuman from Central City, terrorizes the Starling City. Quentin Lance’s mission bounds Oliver Queen to ask Ray (Atom) for help.
Ra’s al Ghul finally makes Oliver an offer he can’t refuse. The team joins Oliver on his journey to Nanda Parbat where a heartbroken Felicity decides to take matters into her own hands.
Oliver goes through a transformation; Laurel asks Felicity and Diggle to help Nyssa face the League of Assassins.
Oliver must complete two final tasks before becoming the next Ra’s al Ghul; Nyssa is threatened; Malcolm makes an offer to the team; Thea visits Roy.
Ra’s al Ghul sets his plan in motion, putting everyone in danger; Oliver must decide if he is strong enough to handle his new role – and what it will mean for his team and his soul.